On the basis of petrogeochemical data, the volcanic lavas of Baimianxia Formation can be classified into two major parts. These are a high TiO2 (>1%) type situated in lower part with high-grade metamorphism, and low TiO2 (<1%) type situated in upper part with low-grade metamorphism. The samples of basalts and andesites show they are derived from depleted mantle source similar to N-MORB. Finally, the authors conclude that the lavas in upper part of Baimianxia Formation represent the geological records of rift-related volcanism in Middle Proterozoic.