Bairendaba and Weilasituo are two silver-polymetallic deposits discovered in recent years in eastern Inner Mongolia. Mineragraphic studies by using the SEMEDX revealed the modes of occurrence of the silver-bearing minerals such as allargentium, dyscrasite, argentobismutite, freibergite and native silver. Metallic minerals in these two deposits are summarized systematically, including their modes of occurrence and formation sequences. The commonly existent jelly-like pyrite is regarded as the product of the earliest ore-forming stage, suggesting a hot water sedimentary environment at low temperature. During the later meso-hypothermal ore-forming process, the assemblage of pyrite + sphalerite + galena + pyrrhotite + chalcopyrite + arsenopyrite + cassiterite was formed. Subsequently, these minerals were crushed and mylonitized intensely, and the ores were characterized by plastic deformation-brecciated and mylonitic structure.