Xiaohaizi syenite complex located within Tarim Basin is an important part of Permian Tarim Large Igneous Provinces (LIPs). SIMS zircon U-Pb analysis yields Early Permian age of (279.7±2.0) Ma, and coeval with diabase and quartz syenite porphyry dikes in the same area. Based on mineralogical composition, it can be categorized into fayalite syenite and amphibole syenite. Xiaohaizi syenites are ferroan, alkaline series and enriched in LREEs relative to HREEs with pronounced positive Eu anomalies, but no negative Nb and Ta anomalies. Geochemical and Sr-Nd isotopic compositions [(87Sr/86Sr)i=0.7033~0.7038, εNd(t)=+3.1~+3.8] indicate that they were derived from a depleted mantle source without crustal assimilation.