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ChemInform Abstract: Ruthenium-Catalyzed C—C Bond Cleavage of 2H-Azirines: A Formal [3 + 2 + 2] Cycloaddition to Fused Azepine Skeletons.
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文摘
The presented approach features an unprecedented ruthenium-catalyzed C—C bond cleavage of 2H-azirines at room temperature which allows access to N-containing seven-membered rings via reactions with diynes.

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