Effect of Sintering Additives on Relative Density and Li-ion Conductivity of Nb-Doped Li₇La₃ZrO₁₂ Solid Electrolyte

详细信息    查看全文

• 作者：Nataly Carolina Rosero-Navarro ; Taira Yamashita ; Akira Miura ; Mikio Higuchi and Kiyoharu Tadanaga
• 刊名：Journal of the American Ceramic Society
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：100
• 期：1
• 页码：276-285
• 全文大小：1133K
• ISSN：1551-2916

文摘

Lithium ion conductors with garnet-type structure are promising candidates for applications in all solid-state lithium ion batteries, because these materials present a high chemical stability against Li metal and a rather high Li⁺ conductivity (10⁻³–10⁻⁴ S/cm). Producing densified Li-ion conductors by lowering sintering temperature is an important issue, which can achieve high Li conductivity in garnet oxide by preventing the evaporation of lithium and a good Li-ion conduction in grain boundary between garnet oxides. In this study, we concentrate on the use of sintering additives to enhance densification and microstructure of Li₇La₃ZrNbO₁₂ at sintering temperature of 900°C. Glasses in the LiO₂-B₂O₃-SiO₂-CaO-Al₂O₃ (LBSCA) and BaO-B₂O₃-SiO₂-CaO-Al₂O₃ (BBSCA) system with low softening temperature (<700°C) were used to modify the grain-boundary resistance during sintering process. Lithium compounds with low melting point (<850°C) such as LiF, Li₂CO₃, and LiOH were also studied to improve the rearrangement of grains during the initial and middle stages of sintering. Among these sintering additives, LBSCA and BBSCA were proved to be better sintering additives at reducing the porosity of the pellets and improving connectivity between the grains. Glass additives produced relative densities of 85–92%, whereas those of lithium compounds were 62–77%. Li₇La₃ZrNbO₁₂ sintered with 4 wt% of LBSCA at 900°C for 10 h achieved a rather high relative density of 85% and total Li-ion conductivity of 0.8 × 10⁻⁴ S/cm at room temperature (30°C).