New 3 D Tubular Porous Structure of an Organic-Zincophosphite Framework with Interesting Gas Adsorption and Luminescence Properties

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• 作者：Prof. Chih-Min Wang ; Dr. Li-Wei Lee ; Tsung-Yuan Chang ; Bing-Lun Fan ; Chih-Ling Wang ; Prof. Hsiu-Mei Lin and Prof. Kuang-Lieh Lu
• 刊名：Chemistry - A European Journal
• 出版年：2016
• 出版时间：November 2, 2016
• 年：2016
• 卷：22
• 期：45
• 页码：16099-16102
• 全文大小：1609K
• ISSN：1521-3765

文摘

A new 3D tubular zinc phosphite, Zn₂(C₂₂H₂₂N₈)_0.5(HPO₃)₂⋅H₂O (1), incorporating a tetradentate organic ligand was synthesized under hydro(solvo)thermal conditions and structurally characterized by single-crystal X-ray diffraction. Compound 1 is the first example of inorganic zincophosphite chains being interlinked through 1,2,4,5-tetrakis(imidazol-1-ylmethyl)benzene to form a tubular porous framework with unusual organic–inorganic hybrid channels. The thermal and chemical stabilities, high capacity for CO₂ adsorption compared to that for N₂ adsorption, and interesting optical properties of LED devices fabricated using this compound were also studied.