Structure of Nano-sized CeO₂ Materials: Combined Scattering and Spectroscopic Investigations

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• 作者：Huw R. Marchbank ; Adam H. Clark ; Dr. Timothy I. Hyde ; Dr. Helen Y. Playford ; Dr. Matthew G. Tucker ; Dr. David Thompsett ; Dr. Janet M. Fisher ; Dr. Karena W. Chapman ; Kevin A. Beyer ; Dr. Manuel Monte ; Dr. Alessandro Longo and Prof. Gopinathan Sankar
• 刊名：ChemPhysChem
• 出版年：2016
• 出版时间：November 4, 2016
• 年：2016
• 卷：17
• 期：21
• 页码：3494-3503
• 全文大小：2464K
• ISSN：1439-7641

文摘

The structure of several nano-sized ceria, CeO₂, systems was investigated using neutron and X-ray diffraction and X-ray absorption spectroscopy. Whilst both diffraction and total pair distribution functions (PDFs) revealed that in all of the samples the occupancy of both Ce⁴⁺ and O²⁻ are very close to the ideal stoichiometry, the analysis using Reverse Monte Carlo technique revealed significant disorder around oxygen atoms in the nano-sized ceria samples in comparison to the highly crystalline NIST standard. In addition, the analysis revealed that the main differences observed in the pair correlations from various X-ray and neutron diffraction techniques were attributable to the particle size of the CeO₂ prepared by the reported three methods. Furthermore, detailed analysis of the Ce L₃- and K-edge EXAFS data support this finding; in particular the decrease in higher shell coordination numbers with respect to the NIST standard, is attributed to differences in particle size.