Extended Bis(benzothia)quinodimethanes and Their Dications: From Singlet Diradicaloids to Isoelectronic Structures of Long Acenes
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- 作者：Dr. Shaoqiang Dong ; Dr. Tun Seng Herng ; Dr. Tullimilli Y. Gopalakrishna ; Dr. Hoa Phan ; Zheng Long Lim ; Pan Hu ; Prof. Richard D. Webster ; Prof. Jun Ding and Prof. Chunyan Chi
- 刊名：Angewandte Chemie International Edition
- 出版年：2016
- 出版时间：August 1, 2016
- 年：2016
- 卷：55
- 期：32
- 页码：9316-9320
- 全文大小：2086K
- ISSN：1521-3773
文摘
Extended bis(benzothia)quinodimethanes and their dications were synthesized as stable species. The neutral compounds mainly have a quinoidal structure in the ground state but show increased diradical character with extension of the central quinodimethane unit. The dications exhibit similar electronic absorption spectra, NMR spectra, NICS values, and diatropic ring currents to their aromatic all-carbon acene analogues and thus can be regarded as genuine isoelectronic structures of pentacene, hexacene, and heptacene, respectively. Our research gave some insights into the design and synthesis of stable longer acene analogues.