ChemInform Abstract: Enantioselective Synthesis of Hemiaminals via Pd-Catalyzed C—N Coupling with Chiral Bisphosphine Mono-Oxides.
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- 作者：Hongming Li ; Kevin M. Belyk ; Jingjun Yin ; Qinghao Chen ; Alan Hyde ; Yining Ji ; Steven Oliver ; Matthew T. Tudge ; Louis-Charles Campeau and Kevin R. Campos
- 关键词：fused pyrrole derivatives ; fused pyrimidine derivatives ; ring closure reactions ; annulation reactions ; catalysis ; phase-transfer catalysis ; diastereoselective syntheses ; enantioselective syntheses (incl. cis/trans-isomerism) ; oxazine derivatives
- 刊名：ChemInform
- 出版年：2016
- 出版时间：April, 2016
- 年：2016
- 卷：47
- 期：17
- 全文大小：30K
- ISSN：1522-2667
文摘
A novel approach to the enantioselective synthesis of hemiaminals via Pd-catalyzed C—N coupling using commercially available chiral bisphosphine ligands is developed.