A Modulator-Induced Defect-Formation Strategy to Hierarchically Porous Metal-Organic Frameworks with High Stability

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• 作者：Guorui Cai and Prof. Dr. Hai-Long Jiang
• 刊名：Angewandte Chemie International Edition
• 出版年：2017
• 出版时间：January 9, 2017
• 年：2017
• 卷：56
• 期：2
• 页码：563-567
• 全文大小：1574K
• ISSN：1521-3773

文摘

The pore size enlargement and structural stability have been recognized as two crucial targets, which are rarely achieved together, in the development of metal–organic frameworks (MOFs). Herein, we have developed a versatile modulator-induced defect-formation strategy, in the presence of monocarboxylic acid as a modulator and an insufficient amount of organic ligand, successfully realizing the controllable synthesis of hierarchically porous MOFs (HP-MOFs) with high stability and tailorable pore characters. Remarkably, the integration of high stability and large mesoporous property enables these HP-MOFs to be important porous platforms for applications involving large molecules, especially in catalysis.