Water-in-Supercritical CO₂ Microemulsion Stabilized by a Metal Complex

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• 作者：Tian Luo ; Prof. Dr. Jianling Zhang ; Xiuniang Tan ; Chengcheng Liu ; Dr. Tianbin Wu ; Dr. Wei Li ; Xinxin Sang ; Prof. Buxing Han ; Prof. Zhihong Li ; Dr. Guang Mo ; Dr. Xueqing Xing and Prof. Zhonghua Wu
• 刊名：Angewandte Chemie
• 出版年：2016
• 出版时间：October 17, 2016
• 年：2016
• 卷：128
• 期：43
• 页码：13731-13735
• 全文大小：1358K
• ISSN：1521-3757

文摘

Herein we propose for the first time the utilization of a metal complex for forming water-in-supercritical CO₂ (scCO₂) microemulsions. The water solubility in the metal-complex-stabilized microemulsion is significantly improved compared with the conventional water-in-scCO₂ microemulsions stabilized by hydrocarbons. Such a microemulsion provides a promising route for the in situ CO₂ reduction catalyzed by a metal complex at the water/scCO₂ interface.