A Stable Manganese Pincer Catalyst for the Selective Dehydrogenation of Methanol
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- 作者：Marí ; a Andé ; rez-Ferná ; ndez ; Lydia K. Vogt ; Steffen Fischer ; Wei Zhou ; Haijun Jiao ; Marcel Garbe ; Saravanakumar Elangovan ; Dr. Kathrin Junge ; Dr. Henrik Junge ; Prof. Dr. Ralf Ludwig and Prof. Dr. Matthias Beller
- 刊名：Angewandte Chemie
- 出版年：2017
- 出版时间：January 9, 2017
- 年：2017
- 卷：129
- 期：2
- 页码：574-577
- 全文大小：861K
- ISSN：1521-3757
文摘
For the first time, structurally defined manganese pincer complexes catalyze the dehydrogenation of aqueous methanol to hydrogen and carbon dioxide, which is a transformation of interest with regard to the implementation of a hydrogen and methanol economy. Excellent long-term stability was demonstrated for the Mn-PNPiPr catalyst, as a turnover of more than 20 000 was reached. In addition to methanol, other important hydrogen carriers were also successfully dehydrogenated.