Controlled synthesis of poly(vinyl acetate) by traditional radical emulsion polymerization

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• 作者：Yu Guan ; Jingjing Li ; Leishan Shao ; Fei Wang ; Dongyu Dong and Yinghan Wang
• 刊名：Polymer International
• 出版年：2016
• 出版时间：December 2016
• 年：2016
• 卷：65
• 期：12
• 页码：1382-1386
• 全文大小：615K
• ISSN：1097-0126

文摘

A new redox initiation system, potassium persulfate/N,N-dimethylethanolamine, was used to initiate traditional radical emulsion polymerization of vinyl acetate at low temperature. Polymers were characterized using gel permeation chromatography, scanning electron microscopy and dynamic light scattering. The results showed that poly(vinyl acetate) with high molar mass and small dispersity (Đ) was successfully synthesized.