Thin Heterojunctions and Spatially Separated Cocatalysts To Simultaneously Reduce Bulk and Surface Recombination in Photocatalysts

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• 作者：Ang Li ; Xiaoxia Chang ; Zhiqi Huang ; Chengcheng Li ; Yijia Wei ; Dr. Lei Zhang ; Dr. Tuo Wang and Prof. Dr. Jinlong Gong
• 刊名：Angewandte Chemie
• 出版年：2016
• 出版时间：October 24, 2016
• 年：2016
• 卷：128
• 期：44
• 页码：13938-13942
• 全文大小：3863K
• ISSN：1521-3757

文摘

Efficient charge separation and light absorption are crucial for solar energy conversion over solid photocatalysts. This paper describes the construction of Pt@TiO₂@In₂O₃@MnO_x mesoporous hollow spheres (PTIM-MSs) for highly efficient photocatalytic oxidation. TiO₂–In₂O₃ double-layered shells were selectively decorated with Pt nanoparticles and MnO_x on the inner and outer surfaces, respectively. The spatially separated cocatalysts drive electrons and holes near the surface to flow in opposite directions, while the thin heterogeneous shell separates the charges generated in the bulk phase. The synergy between the thin heterojunctions and the spatially separated cocatalysts can simultaneously reduce bulk and surface/subsurface recombination. In₂O₃ also serves as a sensitizer to enhance light absorption. The PTIM-MSs exhibit high photocatalytic activity for both water and alcohol oxidation.