ChemInform Abstract: Synthesis of -Aminonitriles via a FeSO4-Mediated Oxidative Cyanation of Tertiary Amines with Benzoyl Cyanide and Molecular Oxygen or TBHP.
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- 作者：Lianpeng Zhang ; Xin Gu ; Ping Lu and Yanguang Wang
- 刊名：ChemInform
- 出版年：2016
- 出版时间：July, 2016
- 年：2016
- 卷：47
- 期：32
- 全文大小：30K
- ISSN：1522-2667
文摘
Concerning the mechanism, a cascade way involving a Fe-catalyzed oxidation of tertiary amine to iminium ions and trapping them by cyanide anion is suggested.