Postsynthetic Incorporation of a Singlet Oxygen Photosensitizer in a Metal-Organic Framework for Fast and Selective Oxidative Detoxification of Sulfur Mustard
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- 作者：Dr. Ashlee J. Howarth ; Cassandra T. Buru ; Dr. Yangyang Liu ; Ann M. Ploskonka ; Dr. Karel J. Hartlieb ; Monica McEntee ; John J. Mahle ; James H. Buchanan ; Erin M. Durke ; Salih S. Al-Juaid ; Prof. J. Fraser Stoddart ; Jared B. DeCoste ; Prof. Joseph T. Hupp and Prof. Omar K. Farha
- 刊名：Chemistry - A European Journal
- 出版年：2017
- 出版时间：January 1, 2017
- 年：2017
- 卷：23
- 期：1
- 页码：214-218
- 全文大小：1641K
- ISSN：1521-3765
文摘
A fullerene-based photosensitizer is incorporated postsynthetically into a Zr6-based MOF, NU-1000, for enhanced singlet oxygen production. The structural organic linkers in the MOF platform also act as photosensitizers which contribute to the overall generation of singlet oxygen from the material under UV irradiation. The singlet oxygen generated by the MOF/fullerene material is shown to oxidize sulfur mustard selectively to the less toxic bis(2-chloroethyl)sulfoxide with a half-life of only 11 min.