Selective Hydrogen Generation from Formic Acid with Well-Defined Complexes of Ruthenium and Phosphorus-Nitrogen PN3-Pincer Ligand
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- 作者：Dr. Yupeng Pan ; Dr. Cheng-Ling Pan ; Yufan Zhang ; Dr. Huaifeng Li ; Dr. Shixiong Min ; Dr. Xunmun Guo ; Dr. Bin Zheng ; Dr. Hailong Chen ; Addison Anders ; Prof. Zhiping Lai ; Prof. Junrong Zheng and Prof. Kuo-Wei Huang
- 刊名：Chemistry – An Asian Journal
- 出版年：2016
- 出版时间：May 6, 2016
- 年：2016
- 卷：11
- 期：9
- 页码：1357-1360
- 全文大小：679K
- ISSN：1861-471X
文摘
An unsymmetrically protonated PN3-pincer complex in which ruthenium is coordinated by one nitrogen and two phosphorus atoms was employed for the selective generation of hydrogen from formic acid. Mechanistic studies suggest that the imine arm participates in the formic acid activation/deprotonation step. A long life time of 150 h with a turnover number over 1 million was achieved.