Carbocatalysis in Liquid-Phase Reactions
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- 作者：Prof. Dr. Dang Sheng Su ; Dr. Guodong Wen ; Dr. Shuchang Wu ; Prof. Dr. Feng Peng and Prof. Dr. Robert Schlö ; gl
- 刊名：Angewandte Chemie International Edition
- 出版年：2017
- 出版时间：January 19, 2017
- 年：2017
- 卷：56
- 期：4
- 页码：936-964
- 全文大小：5040K
- ISSN：1521-3773
文摘
There is broad interest in metal-free catalysis for sustainable chemistry. Carbocatalysis is a “green” option for catalytic transformations in the gas phase as well as in the liquid phase. This is evident by the numerous reports on gas-phase dehydrogenation and selective oxidation where carbon can be used as a successful alternative to metal oxide systems. Carbocatalysis for liquid-phase reactions, especially for organic synthesis, is an emerging research discipline and has undergone rapid development in recent years. This Review provides a critical analysis on the state-of-the-art of carbocatalysts for liquid-phase reactions, with a focus on the underlying mechanisms as well as the advantages and limitations of metal-free carbocatalysts.