ChemInform Abstract: Z-Selective Hydrothiolation of Racemic 1,3-Disubstituted Allenes: An Atom-Economic Rhodium-Catalyzed Dynamic Kinetic Resolution.

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• 作者：Adrian B. Pritzius and Bernhard Breit
• 关键词：sulfoxides ; sulfones ; sulfenes and derivatives (benzene compounds) ; sulfoxides ; sulfones ; sulfenes and derivatives (acyclic compounds) ; sulfuration ; sulfonation ; S-alkylation ; oxidation ; dehydrogenation ; catalysis ; phase-transfer catalysis ; e/z-selectivity (incl. e/z-isomerism) ; diastereoselective syntheses ; enantioselective syntheses (incl. cis/trans-isomerism)
• 刊名：ChemInform
• 出版年：2016
• 出版时间：April, 2016
• 年：2016
• 卷：47
• 期：18
• 全文大小：33K
• ISSN：1522-2667

文摘

Rh-catalyzed reaction of 1,3-disubstituted allenes (I) and (IV) with mercaptans (II) and subsequent one-pot oxidation results in an efficient formation of Z-allylic sulfones (III) and (V).