ChemInform Abstract: Synthesis of a Polyisobutylene-Tagged fac-Ir(ppy)3 Complex and Its Application as Recyclable Visible-Light Photocatalyst in a Continuous Flow Process.

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• 作者：Daniel Rackl ; Peter Kreitmeier and Oliver Reiser
• 关键词：photochemistry ; radiation chemistry ; chemoluminescence ; catalysis ; phase-transfer catalysis ; dehalogenation ; continuous flow processes ; flow processes ; microreactors ; e/z-selectivity (incl. e/z-isomerism) ; ring closure reactions ; annulation reactions
• 刊名：ChemInform
• 出版年：2016
• 出版时间：April, 2016
• 年：2016
• 卷：47
• 期：17
• 全文大小：26K
• ISSN：1522-2667

文摘

Deiodation of compound (I), deiodation/cyclization of compound (III), and E/Z isomerization of compound (V) are accomplished by photocatalysis using the title iridium(III) complex as highly active, homogeneous, and recyclable catalyst.