ChemInform Abstract: 2-Oxindole Acts as a Synthon of 2-Aminobenzoyl Anion in the K2CO3-Catalyzed Reaction with Enones: Preparation of 1,4-Diketones Bearing an Amino Group and Their Further Transformations.
详细信息 查看全文
- 作者：Chun-Bao Miao ; Yu-Mei Zeng ; Tong Shi ; Rui Liu ; Peng-Fei Wei ; Xiao-Qiang Sun and Hai-Tao Yang
- 关键词：ketones (benzene compounds) ; C-C bond formation ; ring closure reactions ; annulation reactions ; ring opening reactions ; quinoline derivatives ; azepine derivatives ; indole derivatives ; isoindole derivatives
- 刊名：ChemInform
- 出版年：2016
- 出版时间：April, 2016
- 年：2016
- 卷：47
- 期：20
- 全文大小：26K
- ISSN：1522-2667
文摘
The potassium carbonate-catalyzed reaction of oxindoles with enones proceeds under the assistance of atmospheric oxygen via a cascade Michael addition/oxidation/ring cleavage process.