文摘
Pd nanoparticles were successfully encapsulated inside mesoporous silicalite-1 nanocrystals (Pd@mnc-S1) by a one-pot method. The as-synthesized Pd@mnc-S1 with excellent stability functioned as an active and reusable heterogeneous catalyst. The unique porosity and nanostructure of silicalite-1 crystals endowed the Pd@mnc-S1 material general shape-selectivity for various catalytic reactions, including selective hydrogenation, oxidation, and carbon–carbon coupling reactions.