Effervescence-assisted dispersive solid-phase extraction using ionic-liquid-modified magnetic β-cyclodextrin/attapulgite coupled with high-performance liquid chromatography for fungicide detection in honey and juice

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• 作者：Xiaoling Wu ; Miyi Yang ; Haozhe Zeng ; Xuefei Xi ; Sanbing Zhang ; Runhua Lu ; Haixiang Gao and Wenfeng Zhou
• 刊名：Journal of Separation Science
• 出版年：2016
• 出版时间：November 2016
• 年：2016
• 卷：39
• 期：22
• 页码：4422-4428
• 全文大小：3310K
• ISSN：1615-9314

文摘

In this study, a simple effervescence-assisted dispersive solid-phase extraction method was developed to detect fungicides in honey and juice. Most significantly, an innovative ionic-liquid-modified magnetic β-cyclodextrin/attapulgite sorbent was used because its large specific surface area enhanced the extraction capacity and also led to facile separation. A one-factor-at-a-time approach and orthogonal design were employed to optimize the experimental parameters. Under the optimized conditions, the entire extraction procedure was completed within 3 min. In addition, the calibration curves exhibited good linearity, and high enrichment factors were achieved for pure water and honey samples. For the honey samples, the extraction efficiencies for the target fungicides ranged from 77.0 to 94.3% with relative standard deviations of 2.3–5.44%. The detection and quantitation limits were in the ranges of 0.07–0.38 and 0.23–1.27 μg/L, respectively. Finally, the developed technique was successfully applied to real samples, and satisfactory results were achieved. This analytical technique is cost-effective, environmentally friendly, and time-saving.