Controllable Remote C−H Bond Functionalization by Visible-Light Photocatalysis

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• 作者：Xiao-Qiang Hu ; Dr. Jia-Rong Chen and Prof. Dr. Wen-Jing Xiao
• 刊名：Angewandte Chemie International Edition
• 出版年：2017
• 出版时间：February 13, 2017
• 年：2017
• 卷：56
• 期：8
• 页码：1960-1962
• 全文大小：1289K
• ISSN：1521-3773

文摘

Remote control: New strategies for the activation of remote C(sp³)−H bonds by photoredox-catalyzed (PC) radical translocation via O- and N-centered radicals have recently been described. These methods enable the controlled and site-selective functionalization of inert C(sp³)−H bonds and provide new opportunities for reaction design (HAT=hydrogen atom transfer).