Implementing Metal-to-Ligand Charge Transfer in Organic Semiconductor for Improved Visible-Near-Infrared Photocatalysis

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• 作者：Yanrui Li ; Zhaowu Wang ; Tong Xia ; Huanxin Ju ; Ke Zhang ; Ran Long ; Qian Xu ; Chengming Wang ; Li Song ; Junfa Zhu ; Jun Jiang and Yujie Xiong
• 刊名：Advanced Materials
• 出版年：2016
• 出版时间：August 24, 2016
• 年：2016
• 卷：28
• 期：32
• 页码：6959-6965
• 全文大小：1872K
• ISSN：1521-4095

文摘

The coordination of organic semiconductors with metal cations can induce metal-to-ligand charge transfer, which broadens light absorption to cover the visible–near-infrared (vis–NIR) spectrum. As a proof-of-concept demonstration, the g-C₃N₄-based complex exhibits dramatically enhanced photocatalytic H₂ production with excellent durability under vis–NIR irradiation.