Inside Cover: Carboxylative Coupling of Chloromethyl(hetero)arenes with Allyltrimethoxysilane Catalyzed by Palladium Nanoparticles (Asian J. Org. Chem. 2/2017)
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- 作者：Jiliang Song ; Dr. Xiujuan Feng ; Prof. Yoshinori Yamamoto ; Prof. Abdulrahman I. Almansour ; Dr. Natarajan Arumugam ; Dr. Raju Suresh Kumar and Prof. Ming Bao
- 刊名：Asian Journal of Organic Chemistry
- 出版年：2017
- 出版时间：February 2017
- 年：2017
- 卷：6
- 期：2
- 页码：119
- 全文大小：495K
- ISSN：2193-5815
文摘
Capturing CO2: A new method has been developed for the chemical fixation of CO2 by using allyltrimethoxysilane as a nucleophile in the presence of palladium nanoparticles as a catalyst. The palladium-catalyzed three-component coupling of either (chloromethyl)arenes or (chloromethyl)heteroarenes with allyltrimethoxysilane and carbon dioxide (i.e., a carboxylative Hiyama coupling reaction) successfully produced α,β-unsaturated esters in satisfactory to good yields. More information can be found in the full paper by Ming Bao, Xiujuan Feng et al. on page 177 in Issue 2, 2017 (DOI: 10.1002/ajoc.201600510).