Polyoxometalate Cluster-Incorporated Metal-Organic Framework Hierarchical Nanotubes

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• 作者：Xiaobin Xu ; Shuangming Chen ; Yifeng Chen ; Hongyu Sun ; Li Song ; Wei He and Xun Wang
• 刊名：Small
• 出版年：2016
• 出版时间：June 8, 2016
• 年：2016
• 卷：12
• 期：22
• 页码：2982-2990
• 全文大小：2186K
• ISSN：1613-6829

文摘

A simple method to prepare metal-organic framework (MOF) nanotubes is developed by employing polyoxometalates (POMs) as modulators. The local structure of the MOF nanotubes is investigated combining XANES and EXAFS studies. These nanotubes show both an excellent catalytic performance in the detoxification of sulfur compounds in O₂ atmosphere and a remarkable cycling stability as the anode material for lithium-ion batteries.