Coupling of Carbon Monoxide with Nitrogen Monoxide at a Frustrated Lewis Pair Template

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• 作者：Dr. Ke-Yin Ye ; Dr. Gerald Kehr ; Dr. Constantin G. Daniliuc ; Dr. Lei Liu ; Prof. Dr. Stefan Grimme and Prof. Dr. Gerhard Erker
• 刊名：Angewandte Chemie
• 出版年：2016
• 出版时间：August 1, 2016
• 年：2016
• 卷：128
• 期：32
• 页码：9362-9365
• 全文大小：601K
• ISSN：1521-3757

文摘

Coupling of carbon monoxide with nitrogen monoxide was achieved at a frustrated Lewis pair template. This unique reaction uses hydride as an auxiliary, which reductively activates carbon monoxide at the frustrated Lewis pair. The CO/NO coupling reaction then takes place through a pathway involving a radical reaction in which the hydrogen atom auxiliary is eventually removed again.