ChemInform Abstract: Organocatalytic Enantioselective Vinylogous Aldol Reaction of Allyl Aryl Ketones to Activated Acyclic Ketones.
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- 作者：Zhenzhong Jing ; Xiangbin Bai ; Wenchao Chen ; Gao Zhang ; Bo Zhu and Zhiyong Jiang
- 关键词：C-C bond formation ; organocatalysis ; diastereoselective syntheses ; enantioselective syntheses (incl. cis/trans-isomerism)
- 刊名：ChemInform
- 出版年：2016
- 出版时间：May, 2016
- 年：2016
- 卷：47
- 期：21
- 全文大小：39K
- ISSN：1522-2667
文摘
Conditions for the title reaction between allyl-aryl and allyl-alkyl ketones with a diverse range of trifluoromethyl ketones, -ketoesters, and -keto phosphonates to form aldol adducts with high enantiomeric excesses are described.