ChemInform Abstract: Use of Planar Chiral Ferrocenylphosphine-Gold(I) Complexes in the Asymmetric Cycloisomerization of 3-Hydroxylated 1,5-Enynes.

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• 作者：Zhiyong Wu ; Pascal Retailleau ; Vincent Gandon ; Arnaud Voituriez and Angela Marinetti
• 关键词：ring closure reactions ; annulation reactions ; catalysis ; phase-transfer catalysis ; diastereoselective syntheses ; enantioselective syntheses (incl. cis/trans-isomerism) ; cyclopropane derivatives ; cyclopentane derivatives
• 刊名：ChemInform
• 出版年：2016
• 出版时间：May, 2016
• 年：2016
• 卷：47
• 期：21
• 全文大小：25K
• ISSN：1522-2667

文摘

Planar chiral ferrocenylphosphines give very active gold catalysts for the asymmetric cycloisomerization of 3-hydroxy-1,5-enynes into bicyclo[3.1.0]hexones.