First Synthesis of Continuous Mesoporous Copper Films with Uniformly Sized Pores by Electrochemical Soft Templating
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- 作者：Dr. Cuiling Li ; Bo Jiang ; Dr. Zhongli Wang ; Yunqi Li ; Dr. Md. Shahriar A. Hossain ; Prof. Dr. Jung Ho Kim ; Dr. Toshiaki Takei ; Dr. Joel Henzie ; Prof. Dr. Ö ; mer Dag ; Prof. Dr. Yoshio Bando and Prof. Dr. Yusuke Yamauchi
- 刊名：Angewandte Chemie International Edition
- 出版年：2016
- 出版时间：October 4, 2016
- 年：2016
- 卷：55
- 期：41
- 页码：12746-12750
- 全文大小：3562K
- ISSN：1521-3773
文摘
Although mesoporous metals have been synthesized by electrochemical methods, the possible compositions have been limited to noble metals (e.g., palladium, platinum, gold) and their alloys. Herein we describe the first fabrication of continuously mesoporous Cu films using polymeric micelles as soft templates to control the growth of Cu under sophisticated electrochemical conditions. Uniformly sized mesopores are evenly distributed over the entire film, and the pore walls are composed of highly crystalized Cu.