Limitations with solvent exchange methods for synthesis of colloidal fullerenes

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• 作者：Shenglin Yang^a ; ^b ; Xavier Mulet^a ; Thomas Gengenbach^a ; Lynne Waddington^a ; Aaron Seeber^a ; Mingming Zhen^c ; Chunru Wang^c ; Benjamin W. Muir^a ; ^{ben.muir@csiro.au} ; Georgina K. Such^b ; ^{gsuch@unimelb.edu.au} ; Xiaojuan Hao^a ; ^{xiaojuan.hao@csiro.au}
• 关键词：C60 ; Nanoparticle ; Solvent exchange ; Decomposition
• 刊名：Colloids and Surfaces A: Physicochemical and Engineering Aspects
• 出版年：2017
• 出版时间：5 February 2017
• 年：2017
• 卷：514
• 期：Complete
• 页码：21-31
• 全文大小：2945 K
• 卷排序：514

文摘

Solvent exchange technique of colloidal fullerene synthesis is further explored. Solvent exchange of DMF-C60 is stable in PBS and water, while the THF-C60 is only stable in water. Solvent exchange of THF results in partial oxidation and degradation of C60. DMF evaporative method results in greater oxidation and degradation of C60.