Solvothermal synthesis of a new 3-D mixed-metal sulfide framework, (H1.33tren)[In2.67Sb1.33S8]·tren
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- 作者：John D. Lampkin j.lampkin@pgr.rdg.ac.uk" class="auth_mail" title="E-mail the corresponding author ; Anthony V. Powell a.v.powell@rdg.ac.uk" class="auth_mail" title="E-mail the corresponding author ; Ann M. Chippindale ; a.m.chippindale@rdg.ac.uk" class="auth_mail" title="E-mail the corresponding author
- 关键词：Solvothermal synthesis ; Crystal structure ; Band gap ; Antimony indium sulfide ; Mixed-metal T2 supertetrahedra
- 刊名：Journal of Solid State Chemistry
- 出版年：2016
- 出版时间：November 2016
- 年：2016
- 卷：243
- 期：Complete
- 页码：44-49
- 全文大小：1233 K
文摘
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Preparation and structural characterisation of a new mixed-metal thiometallate.
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The first mixed In(III)/Sb(V) supertetrahedron.
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Optical band gap of 2.7(2) eV.
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Soaking in aqueous alkali-metal solutions leads to removal of ca. 50% of the organic content.