CH bond arylation of anilides inside copper-exchanged zeolites
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- 作者：Bijoy P. Mathewa ; b ; Hyun Ji Yanga ; Himchan Jeona ; Jeong Hyeon Leea ; Jin Chul Kima ; Tae Joo Shinc ; Kyungjae Myungb ; Sang Kyu Kwaka ; skkwak@unist.ac.kr" class="auth_mail" title="E-mail the corresponding author ; Ja Hun Kwaka ; jhkwak@unist.ac.kr" class="auth_mail" title="E-mail the corresponding author ; Sung You Honga ; b ; syhong@unist.ac.kr" class="auth_mail" title="E-mail the corresponding author
- 关键词：Zeolite ; Heterogeneous catalysis ; CH functionalization ; Copper ; Direct arylation
- 刊名：Journal of Molecular Catalysis A: Chemical
- 出版年：2016
- 出版时间：June 2016
- 年：2016
- 卷：417
- 期：Complete
- 页码：64-70
- 全文大小：2454 K
文摘
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H bond arylation of anilides inside copper-exchanged zeolites is presented.
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DFT studies indicate the well-fitted copper-aryl complexes inside zeolite frameworks.
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Electron micrographs, elemental analyses, and reusability study show no observable metal cluster formations or leaching of catalytically active copper species.
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The practical synthetic potential of copper-exchanged zeolites as promising supported molecular catalysts is demonstrated.