Solvent effects on the absorption and emission spectra of novel (E)-4-((4-(heptyloxy)phenyl)diazenyl)benzyl (((9H-fluoren-9-yl)methoxy)carbonyl)-d-alaninate (Fmoc-al-az): Determination of dipole moment by experimental and theoretical study

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• 作者：Tej Varma Y^a ; ^{ytejvarma@gmail.com} ; Devesh S. Agarwal^b ; Amrit Sarmah^c ; Lata Joshi^d ; Rajeev Sakhuja^b ; Debi D. Pant^a ; ^{ddpant@bits-pilani.ac.in}
• 关键词：Azobenzene dye ; Dipole moment ; Solvatochromic shift ; Steady-state spectroscopy ; Density function theory
• 刊名：Journal of Molecular Structure
• 出版年：2017
• 出版时间：5 February 2017
• 年：2017
• 卷：1129
• 期：Complete
• 页码：248-255
• 全文大小：959 K
• 卷排序：1129

文摘

Amino acid derived azo dye derivatives are synthesized. Solvatochromic correlations are used to estimate ground (μg) and excited state (μe) dipole moments. The dipole moments are compared using experimental and DFT calculations.