Bi (NO3)3·5H2O and cellulose mediated Cu-NPs — A highly efficient and novel catalytic system for aerobic oxidation of alcohols to carbonyls and synthesis of DFF from HMF
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- 作者：Diganta Baruaha ; digantabaruah25@gmail.com" class="auth_mail" title="E-mail the corresponding author ; Farhaz L. Hussaina ; Mrinaly Suria ; Ujwal Pratim Saikiaa ; Pinaki Senguptab ; Dipak Kumar Duttab ; Dilip Konwara ; dkonwar@yahoo.co.uk" class="auth_mail" title="E-mail the corresponding author
- 关键词：Cellulose ; Cu-nanoparticles ; Bismuth nitrate ; Oxidation ; Alcohols ; HMF ; Sustainable
- 刊名：Catalysis Communications
- 出版年：2016
- 出版时间：5 March 2016
- 年：2016
- 卷：77
- 期：Complete
- 页码：9-12
- 全文大小：526 K
文摘
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Bi (NO3)3·5H2O and Cu-NPs@Cellulose as a versatile catalyst for oxidation of alcohols
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Oxidation of 5-hydroxymethyl furfural to 2,5-diformylfuran (82% yield)
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Oxidation of secondary aromatic alcohol to ketones with 100% conversion
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Very high efficiency, broader functional group tolerance & short reaction time
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Primary aromatic alcohols to aldehydes (60–80% conv.)