Spin-dependent effects in ethylene polymerization with bis(imino)pyridine iron(II) complexes
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- 作者：Boris Minaeva ; b ; bfmin@rambler.ru" class="auth_mail" title="E-mail the corresponding author ; Alina Baryshnikovab ; Wen-Hua Suna ; whsun@iccas.ac.cn" class="auth_mail" title="E-mail the corresponding author
- 关键词：Ethylene polymerization ; Spin-catalysis ; Spin-orbit coupling ; Bis(imine)pyridyl iron(II) complexes ; Quantum-chemical calculations ; Brookhart-Gibson catalytic cycle
- 刊名：Journal of Organometallic Chemistry
- 出版年：2016
- 出版时间：1 June 2016
- 年：2016
- 卷：811
- 期：Complete
- 页码：48-65
- 全文大小：1795 K
文摘
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<em>Bisem>(imino)pyridyl iron(II) complexes possess the catalytic activity within ethylene polymerization.
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The catalytic polymerization is controlled by the spin-dependent effects.
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The driving force of spin-dependent catalysis is the spin-orbit coupling (SOC).
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The activation barrier for the catalytic ethylene polymerization has the spin-dependent origin.
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The external magnetic field affect on the catalytic ethylene polymerization.