Transition metal ion-directed magnetic behaviors observed in an isostructural heterobinuclear system
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- 作者：Yan Lia ; b ; Chao Zhangb ; Jia-Wen Yub ; En-Cui Yangb ; encui_yang@163.com" class="auth_mail" title="E-mail the corresponding author ; Xiao-Jun Zhaoa ; b ; xiaojun_zhao15@163.com" class="auth_mail" title="E-mail the corresponding author
- 关键词：Lanthanide ; Heterometallic complexes ; Magnetic properties ; Crystal structure
- 刊名：Inorganica Chimica Acta
- 出版年：2016
- 出版时间：24 April 2016
- 年：2016
- 卷：445
- 期：Complete
- 页码：110-116
- 全文大小：1502 K
文摘
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Four {DyIIIMII} analogues with triple carboxylate mediators were reported.
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The {DyIIINiII}, {DyIIIFeII} and {DyIIIZnII} show field-induced SMM behavior.
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The {DyIIICuII} displays slow frequency-independent relaxation by quantum tunneling.
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These magnetic results afford significant information for the 3d-4f SMMs.