A hydrothermal process was used to prepare BiFeO3/N-doped graphene composites. BiFeO3/N-doped graphene exhibits superior photocatalytic activity and stability. The energy band of BiFeO3 bends downward by ∼1.0 eV at the composite interface. Downward band bending leads to rapid electron transfer at the composite interface. Holes and OH are predominant active species in the photo-degradation process.