Recent advancements in dehydrogenative cross coupling reactions for CC bond formation

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• 作者：Begur Vasanthkumar Varun^a ; ¹ ; Jayaraman Dhineshkumar^a ; ¹ ; Kiran R. Bettadapur^a ; ¹ ; Yogesh Siddaraju^a ; ¹ ; Kaliyamoorthy Alagiri^b ; Kandikere Ramaiah Prabhu^a ; ^{prabhu@orgchem.iisc.ernet.in} ; ^{prabhukandikere@gmail.com}
• 关键词：acac ; acetylacetonate ; AIBN ; 2 ; 2&prime ; -azobis(2-methylpropionitrile) ; BPO ; benzoyl peroxide ; bpy ; 2 ; 2&prime ; -bipyridine ; CDC ; cross dehydrogenative coupling ; CDDHC ; cross double dehydrogenative coupling ; DBU ; 1 ; 8-diazabicycloundec-7-ene ; DCE ; 1 ; 2-dichloroethane ; DDQ ; 2 ; 3-dichloro-5 ; 6-dicyano-1 ; 4-benzoquinone ; dmgH2 ; dimethylglyoxime ; dppb ; 1 ; 4-Bis(diphenylphosphino)butane ; DPPE ; ethylenebis(diphenylphosphine) ; DTBP ; tert-butyl peroxide ; HAT ; hydrogen atom transfer ; MTBE ; methyl tert-bu
• 刊名：Tetrahedron Letters
• 出版年：2017
• 出版时间：1 March 2017
• 年：2017
• 卷：58
• 期：9
• 页码：803-824
• 全文大小：4519 K
• 卷排序：58

文摘

Recent advances on CDC reactions for CC bond formations. CDC reactions are the closest to an ideal reaction that researchers have reached. CDC reactions are step economical and atom economical. CDC reactions are complementary to traditional coupling methods. CDC reactions do not need prefunctionalized precursors.