Phosphinidene-bridged binuclear complexes
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- 作者：M. Esther Garcí ; aa ; Daniel Garcí ; a-Vivó ; a ; Alberto Ramosb ; Miguel A. Ruiza ; mara@uniovi.es" class="auth_mail" title="E-mail the corresponding author
- 关键词：Transition metal complexes ; Phosphinidene complexes ; Binuclear complexes ; Synthesis ; Reactivity ; Structure and bonding
- 刊名：Coordination Chemistry Reviews
- 出版年：2017
- 出版时间：1 January 2017
- 年：2017
- 卷：330
- 期：Complete
- 页码：1-36
- 全文大小：7948 K
文摘
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Phosphinidene-bridged complexes react with a great variety of reagents.
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New P-element bonds are easily formed with phosphinidene-bridged complexes.
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Pyramidal phosphinidene ligands display high basicity at the P site.
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Symmetric trigonal planar phosphinidene ligands display electrophilic behaviour.
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Asymmetric trigonal planar ligands behave as polar −P
M+ double bonds.