Unusual metal-ligand charge transfer in ferrocene functionalized μ3-O iron carboxylates observed with Mössbauer spectroscopy
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- 作者：Valeriu Mereacrea ; valeriu.mereacre@kit.edu" class="auth_mail" title="E-mail the corresponding author ; Martin Schlageterb ; Andreas Eichhö ; ferb ; Thomas Bauerc ; Juliusz A. Wolnyc ; Volker Schü ; nemannc ; Annie K. Powella ; b ; annie.powell@kit.edu" class="auth_mail" title="E-mail the corresponding author
- 关键词：Mö ; ssbauer spectroscopy ; Iron ; Metallocenes ; Carboxylate ligands
- 刊名：Journal of Magnetism and Magnetic Materials
- 出版年：2016
- 出版时间：1 June 2016
- 年：2016
- 卷：407
- 期：Complete
- 页码：87-91
- 全文大小：1338 K
文摘
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In this manuscript we describe a mechanism of electron density shift which stabilizes the trapped mixed-valence state.
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The coexistence of ferrocene and ferrocenium in solid state was determined.
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A mixed-valence state at room-temperature and a thermally induced electron transfer with gradual interconversion were observed.
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