Unprecedented salt-promoted direct arylation of acidic sp² CH bonds under heterogeneous Ni-MOF-74 catalysis: Synthesis of bioactive azole derivatives

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• 作者：Huong T.T. Nguyen ; Duc N.A. Doan ; Thanh Truong ; ^{tvthanh@hcmut.edu.vn}
• 关键词：Metal-organic framework ; CH arylation ; Heterogeneous catalyst ; Ni-MOF-74 ; Bioactive azoles
• 刊名：Journal of Molecular Catalysis A: Chemical
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：426
• 期：part_PA
• 页码：141-149
• 全文大小：2594 K
• 卷排序：426

文摘

Our work provides the unprecedented and general heterogeneous Ni-MOFs-catalyzed direct arylation of heterocycles using KCl as promoter. First report using heterogeneous catalysts to approach bioactive azole derivatives. The catalyst could be recovered and reused.