Rhodium(0) nanoparticles supported on nanosilica: Highly active and long lived catalyst in hydrogen generation from the methanolysis of ammonia borane
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- 作者：Derya Ö ; zhava ; Saim Ö ; zkar ; sozkar@metu.edu.tr" class="auth_mail" title="E-mail the corresponding author
- 关键词：AB ; ammonia borane ; Rh2+ ; rhodium(II) ion ; Rh(0) ; rhodium(0) ; nanosilica ; silica nanopowder ; Rh(0)/nanoSiO2 ; nanosilica stabilized rhodium(0) nanoparticles ; TEM ; transmission electron microscopy ; EDX ; energy dispersive X-ray spectroscopy ; XRD ; X-ray diffraction ; XPS ; X-ray photoelectron spectroscopy
- 刊名：Applied Catalysis B: Environmental
- 出版年：2016
- 出版时间：February 2016
- 年：2016
- 卷：181
- 期：Complete
- 页码：716-726
- 全文大小：2593 K
文摘
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Formation kinetics of rhodium(0) nanoparticles supported on silica nanopowder.
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Highly active catalyst in hydrogen generation from the methanolysis of ammonia borane.
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The highest turnover frequency ever reported in methanolysis of ammonia borane.
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Kinetics of methanolysis of ammonia borane catalyzed by rhodium(0) nanoparticels.