Stability of Sc₂O₃ and CeO₂ co-doped ZrO₂ electrolyte during the operation of solid oxide fuel cells: Part II the influences of Mn, Al and Si

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• 作者：Megumi Shimazu^a ; ^b ; ^{megumi.shimazu@jp.toto.com} ; Katsuhiko Yamaji^c ; Toshihiro Isobe^b ; Akira Ueno^a ; Haruo Kishimoto^c ; Ken-ichi Katsumata^d ; Harumi Yokokawa^c ; Kiyoshi Okada^b ; ^d
• 关键词：Decomposition ; Manganese ; Silicon ; Aluminum ; ScSZ ; Phase transformation ; Solid oxide fuel cell
• 刊名：Solid State Ionics
• 出版年：2011
• 出版时间：12 December, 2011
• 年：2011
• 卷：204-205
• 期：Complete
• 页码：120-128
• 全文大小：3021 K

文摘

Mechanisms for decomposition of 10 mol % Sc₂O₃ and 1 mol % CeO₂ co-doped ZrO₂ (10Sc1CeSZ) electrolytes of a cathode-supported tubular-type SOFC during the long term operation for ?#xA0;100 h have been investigated by analyzing SEM, Raman spectroscopy and XPS of decomposed samples and also by additional examination for the effects of impurities (MnO₂, Al₂O₃ and Si) on the decomposition of electrolyte. The valence of manganese at the decomposed parts in the fuel side was found to become higher after the long term operation. This leads to the driving force for the decomposition of 10Sc1CeSZ into two phases by the large oxygen potential gradient developed on the surface in the fuel side. The kinetic factors for formation of new phases are considered to be as follows; the Si component in the fuel can be a trigger to form MnSiO₃ which worked at the nucleation points, and the valence changes of manganese in the electrolyte proceed the decomposition cycles consisting of two phase separation in the zirconia, pulverization of manganese-rich phase and detachment of zirconia-based oxides.