New pillared dioxomolybdenum(VI) complexes with ONS donor ligands and 4,4′-azopyridine spacer: 3D metal-organic supramolecular architectures and DFT calculations
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- 作者：Debanjana Biswala ; Nikhil Ranjan Pramanikb ; nr_pramanik@yahoo.co.in" class="auth_mail" title="E-mail the corresponding author ; Syamal Chakrabartia ; schakrabarti2014@gmail.com" class="auth_mail" title="E-mail the corresponding author ; Michael G.B. Drewc
- 关键词：Dioxomolybdenum(VI) ; Schiff base ligand ; 4 ; 4&prime ; -Azopyridine ; Crystal structure ; Supramolecular interactions ; DFT calculations
- 刊名：Inorganica Chimica Acta
- 出版年：2016
- 出版时间：1 September 2016
- 年：2016
- 卷：451
- 期：Complete
- 页码：92-101
- 全文大小：2337 K
文摘
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New pillared binuclear dioxo-Mo(VI) complexes with ONS donor ligand and 4,4′-azpy.
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Spectral, electrochemical, thermal and structural characterizations of complexes.
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Rectangular cavities are formed via hydrogen bonding and π-π stacking interactions.
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The DFT calculations provide an energetic study of the non-covalent interactions.