Production of H₂-free CO by decomposition of formic acid over ZrO₂ catalysts

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• 作者：Hyun Ju Lee^a ; ¹ ; Dong-Chang Kang^b ; ¹ ; Seung Hee Pyen^b ; Mi Shin^c ; Young-Woong Suh^c ; Haksoo Han^a ; ^{hshan@yonsei.ac.kr} ; Chae-Ho Shin^b ; ^{chshin@chungbuk.ac.kr}
• 关键词：Tetragonal ZrO2 ; HCOOH decomposition ; Acidity ; Dehydration ; IPA-TPD
• 刊名：Applied Catalysis A: General
• 出版年：2017
• 出版时间：5 February 2017
• 年：2017
• 卷：531
• 期：Complete
• 页码：13-20
• 全文大小：2829 K
• 卷排序：531

文摘

ZrO2 catalysts as catalysts for formic acid decomposition. Calcination temperature of ZrO2 affect to catalytic activity. Catalytic activity could be correlated to the acid strength and surface acid density of catalyst. Effect of CO addition is much more significantly than effect of H2O addition.