Carbonaceous Ti-SBA-15 with enhanced activity and durability was prepared.
Tetrahedral Ti species as Lewis acid sites were maximized in the superficial area.
Mesoporous silica framework was protected by a thin film of P123-derived carbon.
The prepared catalyst showed promise for large-scale synthesis of high-quality BDF.
High-quality BDF was fulfilled with the specification of EN14214:2012 standard.
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