Adsorption removal of tannic acid from aqueous solution by polyaniline: Analysis of operating parameters and mechanism

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• 作者：Chencheng Sun ^{dg1425027@smail.nju.edu.cn" class="auth_mail" title="E-mail the corresponding author} ; Bowen Xiong ^{xiong_bowen@foxmail.com" class="auth_mail" title="E-mail the corresponding author} ; Yang Pan ^{panyang@nju.edu.cn" class="auth_mail" title="E-mail the corresponding author} ; Hao Cui ; ^{cuihaonju6@163.com" class="auth_mail" title="E-mail the corresponding author}
• 关键词：Tannic acid (TA) ; Polyaniline (PANI) ; Adsorption ; Continuous flow
• 刊名：Journal of Colloid and Interface Science
• 出版年：2017
• 出版时间：1 February 2017
• 年：2017
• 卷：487
• 期：Complete
• 页码：175-181
• 全文大小：1246 K

文摘

Polyaniline (PANI) prepared by chemical oxidation was studied for adsorption removal of tannic acid (TA) from aqueous solution. Batch adsorption studies were carried out under different adsorbent dosages, pH, ionic strength, initial TA concentration and coexisting anions. Solution pH had an important impact on TA adsorption onto PANI with optimal removal in the pH range of 8–11. TA adsorption on PANI at three ionic strength levels (0.02, 0.2 and 2 mol L⁻¹ NaCl) could be well described by Langmuir model (monolayer adsorption process) and the maximum adsorption capacity was 230, 223 and 1023 mg g⁻¹, respectively. Kinetic data showed that TA adsorption on PANI fitted well with pseudo-second-order model (controlled by chemical process). Among the coexisting anions tested, PO₄³⁻ significantly inhibited TA adsorption due to the enhancement of repulsive interaction. Continuous flow adsorption studies indicated good flexibility and adaptability of the PANI adsorbent under different flow rates and influent TA concentrations. The mechanism controlling TA adsorption onto PANI under different operating conditions was analyzed with the combination of electrostatic interactions, hydrogen bonding, π-π interactions and Van der Waals interactions.