Using imdazole-2-carboxylic and biimdazole-4,4′-dicarboxylic acid to construct Keggin-based mono-nuclear Ag+ subunit and double Cl-capped tri-nuclear Cu+ clusters
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- 作者：Ai-Xiang Tian ; Xue Hou ; Jun Ying ; Guo-Cheng Liu ; Ya-Li Ning ; Tian-Jiao Li ; Xiu-Li Wang
- 关键词：Keggin-type polyoxometalate ; Electrochemical behavior ; Photocatalytic properties ; Fluorescent properties
- 刊名：Inorganica Chimica Acta
- 出版年：2016
- 出版时间：1 January 2016
- 年：2016
- 卷：439
- 期：Complete
- 页码：43-48
- 全文大小：1686 K
文摘
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Three Keggin-based complexes have been obtained with two N-heterocyclic carboxylic acids ligands.
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Complex 3 shows an uncommonly double Cl-capped tri-nuclear CuI cluster.
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The 1H,1′H-Biimdazole-4,4′-dicarboxylic acid ligand is firstly introduced to the POM field.
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The electrochemical behavior of 2, 3 and photocatalytic properties and fluorescent properties of 1–3 are studied.